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Temperature Controllers

These Controllers receive sensor signals and control heaters or other devices to maintain a preset temperature. They can also be used for humidity, pressure, and flowrate control. OMRON also provides temperature and humidity sensors.

Overview Features
Principles Classifications
Engineering Data Further Information

Primary Contents



Temperature Controller Glossary

Glossary of Control Terminology

Hysteresis

ON/OFF control action turns the output ON or OFF based on the set point. The output frequently changes according to minute temperature changes as a result, and this shortens the life of the output relay or unfavorably affects some devices connected to the Temperature Controller. To prevent this from happening, a temperature band called hysteresis is created between the ON and OFF operations.

Hysteresis (Reverse Operation)

Hysteresis_Reverse_Operation_graph

Example:

If a Temperature Controller with a temperature range of 0 to 400 °C has a 0.2% hysteresis, D will be 0.8 °C. If the set point is 100 °C, the output will turn OFF at a process value of 100 °C and will turn ON at a process value of 99.2 °C.

Hysteresis (Forward Operation)

Hysteresis_Forward_Operation)_graph

Example:

If a Temperature Controller with a temperature range of 0 to 400 °C has a 0.2% hysteresis, D will be 0.8 °C. If the set point is 100 °C, the output will turn OFF at a process value of 100 °C and will turn ON at a process value of 100.8 °C.

Offset

Proportional control action causes an error in the process value due to the heat capacity of the controlled object and the capacity of the heater. The result is a small discrepancy between the process value and the set point in stable operation. This error is called offset. Offset is the difference in temperature between the set point and the actual process temperature. It may exist above or below the set point.

Offset_graph

Hunting and Overshooting

ON/OFF control action often involves the waveform shown in the following diagram. A temperature rise that exceeds the set point after temperature control starts is called overshooting. Temperature oscillation near the set point is called hunting. Improved temperature control is to be expected if the degree of overshooting and hunting are low.

Hunting and Overshooting in ON/OFF Control Action

Hunting_and_Overshooting_in_ON/OFF_Control_Action_graph

control cycle and Time-Proportioning Control Action

The control output will be turned ON intermittently according to a preset cycle if P action is used with a relay or SSR. This preset cycle is called the control cycle and this method of control is called timeproportioning control action.

Control_Cycle_and_Time-Proportioning_Control_Action_diagram

Example:

If the control cycle is 10 s with an 80% control output, the ON and OFF periods will be as follows.

Derivative Time

Derivative time is the period required for a ramp-type deviation in derivative control (e.g., the deviation shown in the following graph)that coincides with the control output in proportional control action.The longer the derivative time is the stronger the derivative control action will be.

PD Action and Derivative Time

PD_Action_and_Derivative_Time_graph

Integral Time

Integral time is the period required for a step-type deviation in integral control (e.g., the deviation shown in the following graph) to coincide with the control output in proportional control action. The shorter the integral time is the stronger the integral action will be. If the integral time is too short, however, hunting may result.

PI Action and Integral Time

PI_Action_and_Integral_Time_graph

For constant value control, control is preformed at specific temperatures.

program control tracks target values to make predetermined changes.

The PID constant values and combinations that are used for temperature control depend on the characteristics of the controlled object. A variety of conventional methods that are used to obtain these PID constants have been suggested and implemented based on actual control temperature waveforms. Auto-tuning methods make it possible to obtain PID constants suitable to a variety of controlling objects. The most common types of Auto-tuning are the step response, marginal sensitivity, and limit cycle methods.

step response Method

The value most frequently used must be the set point in this method.Calculate the maximum temperature ramp R and the dead time L from a 100% step-type control output. Then obtain the PID constants from R and L.

Step_Response_Method_graph

Proportional control action begins from start point A in this method.Narrow the width of the proportional band until the temperature starts to oscillate. Then obtain the PID constants from the value of the proportional band and the oscillation cycle time T at that time.

Marginal_Sensitivity_Method_graph

Limit Cycle Method

ON/OFF control begins from start point A in this method. Then obtain the PID constants from the hunting cycle T and oscillation D.

Limit_Cycle_Method_graph

Readjusting PID Constants

PID constants calculated in auto-tuning operation normally do not cause problems except for some particular applications. In those cases, refer to the following diagrams to readjust the constants.

Response to Change in the Proportional Band

Wider

Response_to_Change_in_the_Proportional_Band_Wider_graph

It is possible to suppress overshooting although a comparatively long startup time and set time will be required.

Narrower

Response_to_Change_in_the_Proportional_Band_Narrower_graph

The process value reaches the set point within a comparatively short time and keeps the temperature stable although overshooting and hunting will result until the temperature becomes stable.

Response to Change in Integral Time

Wider

Response_to_Change_in_Integral_Time_Wider_graph

The set point takes longer to reach. It is possible to reduce hunting, overshooting,and undershooting although a comparatively long startup time and set time will be required.

Narrower

Response_to_Change_in_Integral_Time_Narrower_graph

The process temperature reaches the set point within a comparatively short time although overshooting,undershooting, and hunting will result.

Response to Change in Derivative Time

Wider

Response_to_Change_in_Derivative_Time_Wider_graph

The process value reaches the set point within a comparatively short time with comparatively small amounts of overshooting and undershooting. Fine-cycle hunting will result due to the change in process value.

Narrower

Response_to_Change_in_Derivative_Time_Narrower_graph

The process value will take a relatively long time to reach the set point with heavy overshooting and undershooting.

Fuzzy Self-tuning

PID constants must be determined according to the characteristics of the controlled object for proper temperature control. The conventional Temperature Controller incorporates an auto-tuning function to calculate PID constants. In that case, it is necessary to give instructions to the Temperature Controller to trigger the autotuning function. Furthermore, temperature disturbances may result if the limit cycle is adopted. The Temperature Controller in fuzzy selftuning operation determines the start of tuning and ensures smooth tuning without disturbing temperature control. In other words, the fuzzy self-tuning function makes it possible to adjust PID constants according to the characteristics of the controlled object.

Fuzzy Self-tuning in 3 Modes

PID constants are calculated by tuning when the set point changes.

When an external disturbance affects the process value, the PID constants will be adjusted and kept in a specified range.

If hunting results, the PID constants will be adjusted to suppress hunting.

auto-tuning with a Conventional Temperature Controller

auto-tuning (AT) Function:
A function that automatically calculates
optimum PID constants for controlled objects.

Features:
(1) Tuning will be performed when the AT instruction is given.
(2) The limit cycle signal is generated to oscillate the temperature before tuning.

Auto-tuning_with_a_Conventional_Temperature_Controller_graph

Self-tuning

Self-tuning (ST) Function:
A function that automatically calculates optimum PID constants for controlled objects.

Features:
(1) Whether to perform tuning or not is determined by the Temperature Controller.
(2) No signal that disturbs the process value is generated.

Self-tuning_graph1

Self-tuning

Self-tuning is supported by the E[]S. Trends in temperature changes are used to automatically calculate and set a suitable proportional band.

Self-tuning_graph2

PID Control and Tuning Methods for Temperature Controllers

ModelPIDTwo PIDTwo PID + Fuzzy
Type of PID
E5[]N (See note.)AT, ST**
E5[]KAT, ST
E5[]SST*
E5ZNAT
E5ZDATAT
E5ZEAT
C200H-TCAT
C200H-TVAT
C200H-PIDAT
CQM1-TCAT

ST: Fuzzy self-tuning, ST*: Self-tuning, ST**: Executed only for SP changes,AT: Autotuning

Note:Not including the E5ZN

Control Outputs

Control_Outputs_diagram

Relay output:
Contact relay output used for control methods with comparatively low switching frequencies.

SSR output:
Non-contact solid-state relay output for switching 1 A maximum.

Voltage output (ON/OFF output):
ON/OFF pulse output at 5, 12, or 24 VDC externally connected to a high-capacity SSR. ON/OFF action is ideal for high switching frequency and PID action is ideal for time-proportioning control action.

Current output:
Continuous 4- to 20-mA or 0- to 20-mA DC output used for driving power controllers and electromagnetic valves. Ideal for high-precision control. A preset linear output is produced if the load resistance falls below allowable levels.

Voltage output (Linear output):
Continuous 0 to 5 or 0 to 10 VDC output used for driving pressure controllers.Ideal for high-precision control.

Glossary of Alarm Terminology

The Temperature Controller compares the process value and the preset alarm value, turns the alarm signal ON, and displays the type of alarm in the preset operation mode.

Deviation Alarm

The deviation alarm turns ON according to the deviation from the set point in the Temperature Controller.

Setting Example

Alarm temperature is set to 110 °.

The alarm set point is set to 10 °C.

Deviation_Alarm_diagram

Absolute-value Alarm

The absolute-value alarm turns ON according to the alarm temperature regardless of the set point in the Temperature Controller.

Setting Example

Alarm temperature is set to 110 °C.

The alarm set point is set to 110 °C.

Absolute-value_Alarm_diagram

Standby Sequence Alarm

It may be difficult to keep the process value outside the specified alarm range in some cases (e.g., when starting up the Temperature Controller), and the alarm turns ON abruptly as a result. This can be prevented with the standby sequential function of the Temperature Controller. This function makes it possible to ignore the process value right after the Temperature Controller is turned ON or right after the Temperature Controller starts temperature control. In this case, the alarm will turn ON if the process value enters the alarm range after the process value has been once stabilized.

Example of Alarm Output with Standby Sequence Set

Temperature rise

Temperature_rise_graph

Temperature Drop

Temperature_Drop_graph

SSR Failure Alarm

(Applicable models: E5CN)

The SSR Failure Alarm is output when an SSR short-circuit failure is detected. A ct (Current Transformer) is used by the Temperature Controller to detect heater current and it outputs an alarm when a short circuit occurs.

(Three phase (E5CN, E5AN, and E5EN only) and single phase)

Many types of heaters are used to raise the temperature of the controlled object. The ct (Current Transformer) is used by the Temperature Controller to detect the heater current. If the heater's power consumption drops, the Temperature Controller will detect heater burnout from the ct and will output the heater burnout alarm.

Heater_Burnout_Alarm_diagram

The alarm will turn OFF if the process value falls outside alarm operation range. This can be prevented if the process value enters the alarm range and an alarm is output by holding the alarm output until the power supply turns OFF.

Alarm_Latch_graph

LBA (Operates differently in the E5[]K and E5CN)

(Applicable models: E5[]K)

The LBA (loop break alarm) is a function that turns the alarm signal ON by assuming the occurrence of control loop failure if there is no input change with the control output set to the highest or lowest value. Therefore, this function can be used to detect control loop errors.

(Applicable models: E5CN, E5AN, and E5EN)

The LBA (loop break alarm) is a function that turns the alarm signal ON by assuming the occurrence of control loop failure if there is no input change with the deviation above a certain level. Therefore, this function can be used to detect control loop errors.

Configurable Upper and Lower Limit Alarm Settings

(Applicable models: E5[]N and E5[]R)

Configurable_Upper_and_Lower_Limit_Alarm_Settings_diagram

Glossary of Temperature Sensor Terminology

Cold Junction Compensating Circuit

The thermo-electromotive force of the thermocouple is generated according to the temperature difference between the hot and cold junctions. If the cold junction temperature fluctuates, the measurement data will fluctuate even if the hot junction temperature remains stable. For this reason, a separate sensor built into the controller is used to monitor any changes in the cold junction (terminal connected to the thermocouple), and the controller automatically compensates for these changes to keep the cold end of the device at 0 °C. This is called cold junction compensation.

Cold_Junction_Compensating_Circuit_diagram

The thermoelectromotive force VT is calculated from the following formula: VT = V (350 − 20)

Thermoelectromotive_force_VT_formula

Compensating conductor

An actual application may have a sensing point located far away from the Temperature Controller. Compensating conductors are connected to the thermocouple in this case because thermocouple conductors are expensive. The compensating conductor must conform to the characteristics of the thermocouple, otherwise precise temperature sensing will not be possible.

Example of Compensating Conductor Use

Example_of_Compensating_Conductor_Use_diagram

A preset point is added to or subtracted from the temperature detected by the Temperature Sensor of the Temperature Controller to display the process value. The difference between the detected temperature and the displayed temperature is set as an input compensation value.

Input_Shift_fig

Glossary of Output Terminology

Reverse Operation (Heating)

The Temperature Controller in reverse operation will increase control output if the process value is lower than the set point (i.e., if the Temperature Controller has a negative deviation).

Reverse_Operation_(Heating)_graph

Direct Operation (Cooling)

Direct_Operation_(Cooling)_graph

Heating and Cooling Control

Temperature control over a controlled object would be difficult if heating was the only type of control available, so cooling control was also added. Two control outputs (one for heating and one for cooling)can be provided by one Temperature Controller.

Heating_and_Cooling_Control_diagram

MV (Manipulated Variable) Limiter

The upper and lower limits for the MV limiter are set by the upper MV and lower MV settings. When the MV calculated by the Temperature Controller falls outside the MV limiter range, the actual output will be either the upper or lower MV limit.

Manipulated_Variable_Limiter_graph1

With heating and cooling control, the cooling MV is treated as a negative value. Generally speaking then, the upper limit (positive value) is set to the heating output and the lower limit (negative value)is set to the cooling output as shown in the following diagram.

Manipulated_Variable_Limiter_graph2

Rate of Change Limit

The rate of change limit for the MV sets the amount of change that occurs per second in the MV. If the MV calculated by the Temperature Controller changes significantly, the actual output follows the rate of change limiter setting for MV until it approaches the calculated value.

Rate_of_Change_Limit_graph

The overlap band and dead band are set for the cooling output. A negative value here produces an overlap band and a positive value produces a dead band.

Dead_Band_graphs

When adequate control characteristics cannot be obtained using the same PID constants, such as when the heating and cooling characteristics of the controlled object vary significantly, adjust the proportional band on the cooling side (cooling side P) using the cooling coefficient until heating and cooling side control are balanced. P on the heating and cooling control sides is calculated from the following formula.

Heating side P = P

Cooling side P = Heating side P x cooling coefficient

For cooling side P control when heating side characteristics are different, multiply the heating side P by the cooling coefficient.

Heating Side P × 0.8

Heating_Side_P_×_0.8_graph

Heating Side P × 1.5

Heating_Side_P_×_1.5_graph

Positioning-Proportioning Control

This is also called ON/OFF servo control. When a Control Motor or Modutrol Motor with a valve is used in this control system, a potentiometer reads the degree of pening (position) of the control valve, outputs an open and close signal, and transmits the control output to Temperature Controller. The Temperature Controller outputs two signals: an open and close signal.

OMRON uses floating control. This means that the potentiometer does not feed back the control valve position and temperature can be controlled with or without a potentiometer.

Positioning-Proportioning_Control_diagram

Transfer Output

A Temperature Controller with current output independent from control output is available. The process value or set point within the available temperature range of the Temperature Controller is converted into 4- to 20-mA linear output that can be input into recorders to keep the results of temperature control on record. The transfer output will be turned ON between the upper and lower limits if the E5[]K-[]F the Temperature Controller is used.

Transfer_Output_diagram

Glossary of Setting Terminology

Set Limit

The set point range depends on the Temperature Sensor and the set limit is used to restrict the set point range. This restriction affects the transfer output of the Temperature Controller.

Set_Limit_diagram

Multiple Set Points

Two or more set points independent from each other can be set in the Temperature Controller in control operation.

Setting Memory Banks

The Temperature Controller stores a maximum of eight groups of data (e.g., set value and PID constant data) in built-in memory banks for temperature control. The Temperature Controller selects one of these banks in actual control operation.

Setting_Memory_Banks_diagram

set point (SP) Ramp

The SP ramp function controls the target value change rate with the variation factor. Therefore, when the SP ramp function is enabled,some range of the target value will be controlled if the change rate exceeds the variation factor as shown on the right.

Set_Point_Ramp_graph

Remote Set Point (SP) Input

For a set point input - Glossary of Industrial Automation">remote set point input, the Temperature Controller uses an external input ranging from 4- to 20-mA for the target temperature.When the SP - Glossary of Industrial Automation">remote SP function is enabled, the 4- to 20-mA input becomes the remote set point.

Event Input

An event input is an external signal that can be used to control various actions, such as target value switching, equipment or process RUN/STOP, and pattern selection.

The input digital filter parameter is used to set the time constant of the digital filter. Data that has passed through the digital filter appears as shown in the following diagram.

Input_Digital_Filter_graph

Temperature Sensor Glossary

Temperature Sensor Types and Features

Pt100 and JPt100

In January 1, 1989, the JIS standard for platinum resistance thermometers (Pt100) was revised to incorporate the IEC (International Electrotechnical Commission)standard. The new JIS standard was established on April 1, 1989. Platinum resistance thermometers prior to the JIS standard revision are distinguished as JPt100.Therefore, make sure that the correct platinum resistance thermometer is being used.

The following table shows the differences in appearance of the Pt100 and JPt100.

Classification by model
Pt100
(New JIS standard)
E52-P15A
Pt100 is indicated as P.
JPt100
(Previous JIS standard)
E52-PT15A
JPt100 is indicated as PT.

Note:OMRON discontinued production of JPt100 Sensors in March of 2003.

Indicated Temperature when Connecting Pt100 Sensor to JPt100 Input

Indicated_Temperature_when_Connecting_Pt100_Sensor_to_JPt101_Input_graph

Indicated Temperature when Connecting JPt100 Sensor to Pt100 Input

Indicated_Temperature_when_Connecting_JPt100_Sensor_to_Pt101_Input_graph

Temperature Sensor Construction

SheathedStandard
Features・ Compared with standard models, these sensors have high resistance to vibration and shock.
・ The finished outer diameter is extremely slim enabling easy insertion in small sensing objects, and low heat capacity enables fast response to changes in temperature.
・ The sheathed tubing is flexible, enabling insertion and measurement within complex machinery.
・ The airtight construction provides high sensitivity and prevents oxidation, for superior heat resistance and durability.
・ Compared with the sheathed models, the thick tubing diameter provides strength and durability.
・ Slow response speed.
Internal
structure

Thermocouple Measuring Junction Construction

Non-grounded modelsGrounded models
Features・ Fully isolated measuring junction and protective tubing
・ Response is inferior to grounded models, but noise resistance is high.
・ Widely used for general-purpose applications.
・ Soldered ends of measuring junction protective tubing.
・ Fast response but noise resistance is low.
・ High productivity, low-cost model.
Internal
construction
The sheath and thermocouple are insulated.The sheath and thermocouple are not insulated.

Terminal Block Appearance

Exposed lead wiresExposed terminalsEnclosed terminals
FeaturesLead wires directly extend from protective tubing, enabling low-cost manufacturing without requiring more space.
→ For building into machines
Construction uses exposed terminal screws for easy maintenance.
→ For general-purpose indoor use
Construction with enclosed terminal screws enables broad range of applications.
→ For indoor industrial equipment
Appearance
Permissible
temperature
in
dry air
• Sleeve Standard: 0 to +70°C
Heat Resistive: 0 to +100°C
• Lead wire (platinum resistance thermometer)
Standard (vinyl-covered): −20 to +70°C
Heat resistive (glass-wool-covered with stainless-steel external shield): 0 to 180 °C
• Lead wire (compensating conductor)
Standard (vinyl-covered): −20 to +70°C
Heat resistive (glass-wool-covered with stainless-steel external shield): 0 to 150°C
Permissible temperature in dry air for terminal box: 0 to +100°CPermissible temperature in dry air for terminal box: 0 to +80°C

Temperature Sensor Thermal Response

A delay will occur before the temperature sensor reaches the temperature of the sensing object. This delay is generally referred to as the response time. JIS standards specify the response characteristics of a temperature sensor as the time required by the sensor to reach 63.2% of the indicated value for the temperature of the sensing object starting from when the temperature sensor touches the sensing object. Refer to the test results provided in the tables on the right.

Thermal Response of Sheathed Temperature Sensors

Protective tubing: SUS316

Test conditionsProtective tubingdia. (mm)Indicated valueStatic water, room temperature to 100 °C
1.0 dia.1.6 dia.3.2 dia.4.8 dia.6.4 dia.
ThermocoupleThermocoupleThermocouplePlatinum
resistance
thermometer
ThermocouplePlatinum
resistance
thermometer
ThermocouplePlatinum
resistance
thermometer
63.2% of indicated
value
0.08 s0.15 s1 s2.5 s1.8 s4.2 s4 s9.9 s

Standard Temperature Sensors

Thermal Response of Standard Thermocouple

Protective tubing: SUS316

Test conditions
Protective tubing
dia. (mm)

Indicated value
Static waterDry air, room temperature to 100°C
12 dia. (thermocouple element dia: 1.6 mm)
Room temperature

to 100°C
100°C to room temperatureStatic airFed air:

1.5 m/s
Fed air:

3 m/s
63.2% of indicated value55 s56 s6 min. 50 s2 min. 2 s1 min. 43 s

Thermal Response of Platinum Resistance Thermometer

Protective tubing: SUS316

Test conditions
Protective tubing
dia. (mm)

Indicated value
Static water, roomtemperature to 100°C
8 dia.10 dia.
63.2% of indicated
value
21.9 s23.6 s

Vibration and Shock Resistance

The testing standards for temperature sensors specified by JIS are provided in the tables on the right. Refer to these standards and provide sufficient margins for the application conditions.

Vibration Resistance

Thermocouple

(Conforms to JIS C1602-1995)

Test itemFrequency(Hz)Doubleamplitude(mm)Testing tim (min)Vibration direction
SweepsDestructionTwo axis directions
including length
direction
Resonance test30 to 1000.052---
Fixed frequency
durability test
1000.02---60

Note:This test is not performed for Sensors with non-metal protective tubing.Fixed frequency durability tests are conducted at 70 Hz when the resonance point is 100 Hz.

(Conforms to JIS C1604-1997)

Frequency (Hz)Acceleration (m/s2)Sweeps per minuteNo. of sweeps
10 to 15010 to 20210

Shock Resistance

Holding the test product on its side, the product is then dropped from a height of 250 mm onto a steel plate 6 mm thick placed on a hard floor. This process is repeated 10 times, after which the product is checked for electrical faults in the measuring junctions and terminal contacts. This test is not performed, however, on products with non-metal protective tubing (conforms to JIS C1602-1995 and JIS C1604-1997).

Permissible Temperature in Dry Air

The permissible temperature in dry air refers to the temperature under which the thermoelectromotive force does not change above the values indicated in the following table when used continuously in static dry air for the time indicated in the following table. The permissible temperature depends on the type of lead wire (thermocouple), protective tubing material,and diameter. The life of thermocouples will generally be extended by lowering the operating temperature. Therefore, use the temperature sensors in conditions that provide sufficient margin in operating temperature beyond the permissible temperature in dry air.

(Conforms to JIS C1602-1995)

ElementtypeContinuoususe (hours)Change inthermoelectromotiveforce ateach temperature(%)
B2000±0.5
R
S
N10000±0.75
K
E
J
T

Sheathed

Thermocouple Permissible Temperature in Dry Air

M: Protective tubing material
D: Protective tubing diameter (mm)

Element M

D
K (CA)InconelK (CA)SUS316J (IC)SUS316
1 dia.---650°C450°C
1.6 dia.---650°C450°C
3.2 dia.---750°C650°C
4.8 dia.---800°C750°C
6.4 dia.1,000°C800°C750°C
8.0 dia.1,050°C900°C750°C

Standard

Thermocouple Permissible Temperature in Dry Air

M: Protective tubing material
D: Protective tubing diameter (mm)

Element M

D
K (CA)SUS310SK (CA)SUS316J (IC)SUS316
10 dia.750°C750°C450°C
12 dia.850°C850°C500°C
15 dia.900°C850°C550°C
22 dia.1,000°C900°C600°C

Permissible Temperature in Dry Air

Element M

D
RPT0RPT1
17 dia.1,400°C
JIS symbolType
PT0Protective tubing: Special
ceramic
PT1Protective tubing: Ceramic
Cat. 1

Reference Material for Temperature Sensors

Thermocouple Standard Potential Difference

Thermocouples generate voltage according to the temperature difference. The potential difference is prescribed by Japanese Industrial Standards (JIS).The following chart gives the potential difference for R, S, K, and J thermocouples when the temperature of the reference junction is 0 °C.E5[]N, E5ZN, and E5[]R conform to standards published in 1995. Other Temperature Controllers conform to standards published in 1981 (listed below).

(Standards Published in 1995)

JIS C 1602-1995 (Unit: μV)

CategoryTemperature
(°C)
0102030405060708090
R standard potential
difference
0054111171232296363431501573
10064772380087995910411124120812941381
2001469155816481739183119232017211222072304
3002401249825972696279628962997309932013304
4003408351236163721382739334040414742554363
5004471458046904800491050215133524553575470
6005583569758125926604161576273639065076625
7006743686169807100722073407461758377057827
8007950807381978321844685718697882389509077
9009205933394619590972098509980101111024210374
100010506106381077110905110391117311307114421157811714
110011850119861212312260123971253512673128121295013089
120013228133671350713646137861392614066142071434714488
130014629147701491115052151931533415475156161575815899
140016040161811632316464166051674616887170281716917310
150017451175911773217872180121815218292184311857118710
160018849189881912619264194021954019677198141995120087
170020222203562048820620207492087721003---------
S standard potential
difference
0055113173235299365433502573
10064672079587295010291110119112731357
2001441152616121698178618741962205221412232
3002323241525072599269227862880297430693164
4003259335534513548364537423840393840364134
5004233433244324532463247324833493450355137
6005239534154435546564957535857596160656170
7006275638164866593669968066913702071287236
8007345745475637673778378938003811482268337
9008449856286748787890090149128924293579472
10009587970398199935100511016810285104031052010638
110010757108751099411113112321135111471115901171011830
120011951120711219112312124331255412675127961291713038
130013159132801340213523136441376613887140091413014251
140014373144941461514736148571497815099152201534115461
150015582157021582215942160621618216301164201653916658
160016777168951701317131172491736617483176001771717832
170017947180611817418285183951850318609---------
K standard potential
difference
003977981203161220232436285132673682
1004096450949205328573561386540694173407739
200813885398940934397471015310561109711138211795
30012209126241304013457138741429314713151331555415975
40016397168201724317667180911851618941193661979220218
50020644210712149721924223502277623203236292405524480
60024905253302575526179266022702527447278692828928710
70029129295482996530382307983121331628320413245332865
80033275336853409334501349083531335718361213652436925
90037326377253812438522389183931439708401014049440885
100041276416654205342440428264321143595439784435944740
110045119454974587346249466234699547367477374810548473
120048838492024956549926502865064451000513555170852060
130052410527595310653451</